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Treffer: Introduction to Formal Graphs, a new approach to the classical formalism.

Title:
Introduction to Formal Graphs, a new approach to the classical formalism.
Authors:
Vieil E; Laboratory of Electrochemistry and Physico-chemistry of Materials and Interfaces, Mixed Unit of Research 5631, CNRS and INP-Grenoble, Grenoble, 1130 rue de la piscine, 38402 Saint Martin d'Hères, France. Eric.Vieil@lepmi.inpg.fr
Source:
Physical chemistry chemical physics : PCCP [Phys Chem Chem Phys] 2007 Aug 07; Vol. 9 (29), pp. 3877-96. Date of Electronic Publication: 2007 Jun 04.
Publication Type:
Journal Article
Language:
English
Journal Info:
Publisher: Royal Society of Chemistry Country of Publication: England NLM ID: 100888160 Publication Model: Print-Electronic Cited Medium: Print ISSN: 1463-9076 (Print) Linking ISSN: 14639076 NLM ISO Abbreviation: Phys Chem Chem Phys Subsets: MEDLINE
Imprint Name(s):
Original Publication: Cambridge [England] : Royal Society of Chemistry, c1999-
Entry Date(s):
Date Created: 20070720 Date Completed: 20070928 Latest Revision: 20161124
Update Code:
20250114
DOI:
10.1039/b700797c
PMID:
17637980
Database:
MEDLINE

Weitere Informationen

The creation of a purely graphic language called Formal Graphs for modelling many physical and physico-chemical systems is described. It represents an improvement over traditional equivalent circuits used for modelling systems made of individual components and over bond graphs used mainly in physico-chemistry. In contradistinction with these graphs, which represent graphically only mounting equations and maintain algebraic equations for describing components behaviour, a formal graph is an oriented graph incorporating all the information contained in a usual algebraic model. Combination of paths considerably extends use to domains that were not accessible to quantitative graphs, such as relaxation processes, chemical reactivity or mass-transfer. Moreover, inclusion of space derivation allows representing graphically every physical law describing a process involving energy conservation or dissipation, such as particle diffusion. Physical meaning can be deduced from paths in a graph that can be followed by processes, as illustrated by the exponent of fractional derivation, which appears as bearing the information on the proportion of conserved versus dissipated energy. The numerous examples given in this introduction address several domains, electrodynamics, mechanics, thermodynamics, and physico-chemistry. They show common graph structures that reveal a striking unity of our classical formalism, bringing transversal insight and opening a new route towards unification. Differences also appear that are subjects of interrogation.