Result: Combinatorial method for the development of a catalyst promoting hydrogen uptake
Title:
Combinatorial method for the development of a catalyst promoting hydrogen uptake
Authors:
Source:
Proceedings of the 9th International Symposium on Metal-Hydrogen Systems, Fundamentals and Applications (MH2004), September 5-10, 2004, Cracow, PolandJournal of alloys and compounds. 404-6:699-705
Publisher Information:
Lausanne: Elsevier, 2005.
Publication Year:
2005
Physical Description:
print, 17 ref
Original Material:
INIST-CNRS
Subject Terms:
Inorganic chemistry, Chimie minérale, Crystallography, Cristallographie cristallogenèse, Metallurgy, welding, Métallurgie, soudage, Condensed state physics, Physique de l'état condensé, Sciences exactes et technologie, Exact sciences and technology, Chimie, Chemistry, Chimie generale et chimie physique, General and physical chemistry, Théorie des réactions, cinétique générale. Catalyse. Nomenclature, documentation chimique, informatique chimique, Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry, Catalyse, Catalysis, Réactions catalytiques, Catalytic reactions, Sciences appliquees, Applied sciences, Energie, Energy, Combustibles, Fuels, Combustibles de remplacement. Production et utilisation, Alternative fuels. Production and utilization, Hydrogène, Hydrogen, Activité catalytique, Catalyst activity, Actividad catalítica, Argent, Silver, Plata, Catalyseur, Catalyst, Catalizador, Chimisorption, Chemisorption, Adsorción química, Cinétique, Kinetics, Cinética, Composition non stoechiométrique, Non stoichiometric composition, Composición no estequiométrica, Couche mince, Thin film, Capa fina, Cuivre, Copper, Cobre, Effet pression, Pressure effect, Efecto presión, Energie activation, Activation energy, Energía activación, Modélisation, Modeling, Modelización, Métal transition, Transition metal, Metal transición, Méthode combinatoire, Combinatorial method, Método combinatorio, Nickel, Niquel, Palladium, Paladio, Relation empirique, Empirical relation, Relación empírica, Sorption, Sorción, Stockage hydrogène, Hydrogen storage, Gas-solid interaction, Hydrogen storage material, Light absorption, Thin films
Document Type:
Conference
Conference Paper
File Description:
text
Language:
English
Author Affiliations:
Faculty of Sciences, Division of Physics and Astronomy, Vrije Universiteit De Boelelaan 1081, 1081 HV Amsterdam, Netherlands
ISSN:
0925-8388
Rights:
Copyright 2006 INIST-CNRS
CC BY 4.0
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
CC BY 4.0
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
Notes:
Energy
General chemistry and physical chemistry
General chemistry and physical chemistry
Accession Number:
edscal.17453810
Database:
PASCAL Archive
Further Information
A novel optical technique to measure catalytic activity for hydrogen sorption is presented. The catalytic activity of the noble metals of Pd, Ni, Cu and Ag is studied as function of pressure and temperature. The uptake rate is limited by chemisorption as deduced by modelling kinetics. An empirical relation between uptake rate and the measured activation energy is given. The catalytic activity of NbOx is studied as a function of the oxygen concentration determined from electron spectroscopy. The measured activation energy depends strongly on the oxygen concentration and reaches a minimum of 0.6 eV at the highest oxygen content (x = 2.5, i.e. Nb2O5). Pure Nb does not display a significant catalytic efect.