Treffer: IR, Raman, and UV/Vis Spectra of Corannulene for Use in Possible Interstellar Identification

Title:
IR, Raman, and UV/Vis Spectra of Corannulene for Use in Possible Interstellar Identification
Authors:
ROUILLDE, Gaël, JÄGER, Cornelia, STEGLICH, Mathias, HUISKEN, Friedrich, HENNING, Thomas, THEUMER, Gabriele, BAUER, Ingmar, KNÖLKER, Hans-Joachim
Source:
ChemPhysChem (Print). 9(14):2085-2091
Publisher Information:
Weinheim: Wiley, 2008.
Publication Year:
2008
Physical Description:
print, 31 ref
Original Material:
INIST-CNRS
Subject Terms:
Biochemistry, molecular biology, biophysics, Biochimie, biologie moléculaire, biophysique, General chemistry, physical chemistry, Chimie générale, chimie physique, Nanotechnologies, nanostructures, nanoobjects, Nanotechnologies, nanostructures, nanoobjets, Atomic molecular physics, Physique atomique et moléculaire, Condensed state physics, Physique de l'état condensé, Sciences exactes et technologie, Exact sciences and technology, Terre, ocean, espace, Earth, ocean, space, Astronomie, Astronomy, Astronomie fondamentale et astrophysique. Instrumentation, techniques, et observations astronomiques, Fundamental astronomy and astrophysics. Instrumentation, techniques, and astronomical observations, Problèmes fondamentaux d'astrophysique, Fundamental aspects of astrophysics, Processus et interactions moléculaires et chimiques, Molecular and chemical processes and interactions, Systèmes stellaires. Objets et systèmes galactiques et extragalactiques. L'univers, Stellar systems. Galactic and extragalactic objects and systems. The universe, Milieu interstellaire et nébuleuses dans la galaxie, Interstellar medium (ism) and nebulae in milky way, Processus atomiques, moléculaires, chimiques et des grains, Atomic, molecular, chemical, and grain processes, Absorption IR, Infrared absorption, Absorción IR, Chromatographie phase gazeuse, Gas chromatography, Chromatographie phase liquide, Liquid chromatography, Cromatografía fase líquida, Diffusion Raman, Raman scattering, Difusión Ramán, Fonctionnelle densité, Density functional, Funciónal densidad, Hydrocarbure aromatique polycyclique, Polycyclic aromatic hydrocarbons, Matière interstellaire, Interstellar matter, Molécule interstellaire, Interstellar molecules, Méthode fonctionnelle densité, Density functional method, Performance, Spectre IR, Infrared spectra, Spectre Raman, Raman spectra, Spectre UV, Ultraviolet spectra, Spectre absorption, Absorption spectra, Spectrométrie IR, Infrared spectroscopy, Spectrométrie Raman, Raman spectroscopy, Spectrométrie absorption, Absorption spectroscopy, Spectrométrie masse, Mass spectroscopy, IR spectroscopy, UV/ Vis spectroscopy, density functional calculations, polycyclic aromatic hydrocarbons
Document Type:
Fachzeitschrift Article
File Description:
text
Language:
English
Author Affiliations:
Laboratory Astrophysics Group of the Max Planck Institute for Astronomy Institute of Solid State Physics, Friedrich-Schiller Universität Jena Helmholtzweg 3, 07743 Jena, Germany
Max-Planck-lnstitut für Astronomie Königstuhl 17, 69117 Heidelberg, Germany
Department Chemie, Technische Universität Dresden Bergstrasse 66, 01069 Dresden, Germany
ISSN:
1439-4235
Access URL:
http://pascal-francis.inist.fr/vibad/index.php?action=search&terms=20707443
Rights:
Copyright 2009 INIST-CNRS
CC BY 4.0
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
Notes:
Astronomy
Accession Number:
edscal.20707443
Database:
PASCAL Archive

Weitere Informationen

The spectroscopic characterization of corannulene (C20H10) is carried out by several techniques. The high purity of the material synthesized for this study was confirmed by gas chromatography-mass spectrometry (GC-MS). During a high-performance liquid chromatography (HPLC) process, the absorption spectrum of corannulene in the ultraviolet (UV) and visible (vis) ranges is obtained. The infrared (IR) absorption spectrum is measured in Csl pellets, and the Raman scattering spectrum is recorded for pure crystal grains. In addition to room temperature measurements, absorption spectroscopy in an argon matrix at 12 K is also performed in the IR and UV/Vis ranges. The experimental spectra are compared with theoretical Raman and IR spectra and with calculated electronic transitions. All calculations are based on the density functional theory (DFT), either normal or time-dependent (TDDFT). Our results are discussed in view of their possible application in the search for corannulene in the interstellar medium.