Result: Combinatorial discovery of Ni-based binary and ternary catalysts for hydrazine electrooxidation for use in anion exchange membrane fuel cells

Title:
Combinatorial discovery of Ni-based binary and ternary catalysts for hydrazine electrooxidation for use in anion exchange membrane fuel cells
Authors:
SAKAMOTO, Tomokazu, ASAZAWA, Koichiro, SANABRIA-CHINCHILLA, Jean, MARTINEZ, Ulises, HALEVI, Barr, ATANASSOV, Plamen, STRASSER, Peter, TANAKA, Hirohisa
Source:
Journal of power sources (Print). 247:605-611
Publisher Information:
Amsterdam: Elsevier, 2014.
Publication Year:
2014
Physical Description:
print, 48 ref
Original Material:
INIST-CNRS
Subject Terms:
Electrical engineering, Electrotechnique, Energy, Énergie, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Electrotechnique. Electroenergetique, Electrical engineering. Electrical power engineering, Electroénergétique, Electrical power engineering, Conversion directe et accumulation d'énergie, Direct energy conversion and energy accumulation, Conversion électrochimique: piles et accumulateurs électrochimiques, piles à combustibles, Electrochemical conversion: primary and secondary batteries, fuel cells, Energie, Energy, Energie. Utilisation thermique des combustibles, Energy. Thermal use of fuels, Appareils de production et de conversion d'énergie: énergie thermique, énergie électrique, énergie mécanique, etc, Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc, Piles à combustible, Fuel cells, Catalyseur, Catalyst, Catalizador, Chimie combinatoire, Combinatorial chemistry, Química combinatoria, Hydrate, Hydrates, Hidrato, Hydrazine, Hidracina, Méthode combinatoire, Combinatorial method, Método combinatorio, Nickel Composé, Nickel Compounds, Niquel Compuesto, Oxydation, Oxidation, Oxidación, Pile combustible hydrazine, Hydrazine fuel cells, Utilisation, Use, Uso, N2H4, Pile à combustible à membrane échangeuse d'anions, Anion exchange membrane fuel cell, Anion exchange membrane fuel cells, Direct hydrazine hydrate fuel cells, Hydrazine oxidation, Ni-based binary and ternary catalysts
Document Type:
Academic journal Article
File Description:
text
Language:
English
Author Affiliations:
Frontier Technology R & D Division, Daihatsu Motor Co., Ltd., 3000 Yamanoue, Ryuo, Gamo, Shiga 520-2593, Japan
Department of Chemical and Biomolecular Engineering, University of Houston, Houston, TX 77204, United States
Chemical & Nuclear Engineering Department, UNM Center for Emerging Energy Technologies, University of New Mexico, Albuquerque, NM 87131, United States
The Electrochemical Energy, Catalysis, and Materials Science Laboratory, Department of Chemistry, Chemical Engineering Division, Technical University Berlin, 10623 Berlin, Germany
ISSN:
0378-7753
Access URL:
http://pascal-francis.inist.fr/vibad/index.php?action=search&terms=28245603
Rights:
Copyright 2015 INIST-CNRS
CC BY 4.0
Sauf mention contraire ci-dessus, le contenu de cette notice bibliographique peut être utilisé dans le cadre d’une licence CC BY 4.0 Inist-CNRS / Unless otherwise stated above, the content of this bibliographic record may be used under a CC BY 4.0 licence by Inist-CNRS / A menos que se haya señalado antes, el contenido de este registro bibliográfico puede ser utilizado al amparo de una licencia CC BY 4.0 Inist-CNRS
Notes:
Electrical engineering. Electroenergetics

Energy
Accession Number:
edscal.28245603
Database:
PASCAL Archive

Further Information

Ni-based catalysts, binary Ni-M (with M = Mn, Fe, Zn, La) and ternary Ni-Mn-Fe and Ni-Zn-La were investigated for hydrazine oxidation in direct hydrazine hydrate fuel cell anodes by a temperature controlled 16-channel electrochemical combinatorial array. The binary Ni0.8Zn0.2 and Ni0.9La0.1 catalysts are significantly more active than the Ni reference catalyst for hydrazine oxidation. While the best Ni0.8Zn0.1La0.1 ternary catalyst is close to the high active binary catalysts in composition. Additionally, Ni0.6Fe0.2Mn0.2 catalysts also showed high catalytic activity for hydrazine oxidation in alkaline media over standard Ni catalyst. The X-ray diffraction (XRD) analysis indicated that the alloying effect between Ni and added elements improves the catalytic activity for hydrazine oxidation. As a result of the screening tests and our previous research, unsupported binary Ni0.87Zn0.13 and Ni0.9La0.1 catalysts were synthesized by spray pyrolysis and tested in a direct hydrazine hydrate fuel cell MEA (DHFC) producing 486 mW cm-2 and 459 mW cm-2, respectively.