Result: X-ray lithography for devices with high aspect ratio polymer submicron structures
University of Saskatchewan, Department of Electrical and Computer Engineering, 57 Campus Dr, Saskatoon, SK, S7N 5A9, Canada
Forschungszentrum Karlsruhe, Institut für Mikrostrukturtechnik (IMT), Postfach 3640, 76021 Karlsruhe, Germany
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Further Information
Novel applications for micro systems, such as commercial devices for information transfer and biomedical analysis, nowadays require reduced lateral dimensions in the low submicron range. Applications like metallic band-pass-filters and transparent fluidic systems for single molecule analysis, both presented in this paper, at the same time depend on structure heights (thickness) of several microns, leading to high aspect ratios (thickness/minimum feature size, AR). The paper presents enhancements of process conditions (masking, coating, exposure, development) in high resolution X-ray lithography that allow the fabrication of the aforementioned devices. Spin coated Polymethylmethacrylate (PMMA) films of 2-11 μm thickness were structured using Synchrotron radiation (λc≈ 0.4 nm) and subsequent dip developed in GG developer. Three PMMA grades originally developed for electron beam lithography were characterized for this application. The contrast of the resist/developer systems examined is reduced at exposure doses below 1 kJ/cm3. Therefore, the exposure dose was set well above this value (nominally, to 4 kJ/cm3). Resist collapse due to surface tension during drying after development limits the achievable AR. The maximum AR is a function of the structure height for walls and columns. Increased pre-bake temperatures (180 °C instead of 111 °C) and a reduced surface tension in the development rinser (10 ppm fluorosurfactant) result in more stable structures and increase the achievable AR. AR exceeding 12 could be demonstrated for feature sizes down to 520 nm in 7.3 μm thick resists. Some devices presented were replicated in metal.