Result: Investigation of resistance change characteristics with applied electric field on Ag/chalcogenide As2S3 and As40Ge10Se15S35 thin film structure
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In the present work, we investigated the effects of frequency, temperature and applied electric field directions on the resistance change characteristics ofAg/As2S3 and Ag/As40Ge10Se15S35 chalcogenide thin film structures. In off-state operation mode, the resistance changes with the temperature and the frequency showed the intrinsic semiconductor characteristics with the resistance and the capacitance component. On the other hand, the metallic conductor characteristics with only resistance component were observed in on-state operation mode. And we obtained that the Rreverse/Rforward ratio of Ag/As2S3 thin film was ∼106, which is 10 times larger than that of Ag/As40-Ge10Se15S35 thin film. Both values are acceptable as a high sensing margin for read-out of storage data in Ag doped chalcogenide thin film. And high recording speed (60-70 ns) and low threshold voltage were achieved when the Ag/chalcogenide thin film layer thickness ratio is about 10%. Additionally, the Ag/chalcogenide layer thickness ratio was closely related to the reversible resistance change amount. Therefore, we believe that the Ag/chalcogenide films are effective materials for non-volatile, low current and, potentially, low cost for the next generation of non-volatile memory applications such as RFID chips to replace EEPROM.