Treffer: The effect of annealing temperature on the electrical properties of metal-ferroelectric (PbZr0.53Ti0.47O3 ) -insulator (ZrO2)-semiconductor (MFIS) thin-film capacitors
Department of Materials Engineering, Mingchi University of Technology, Taipei 243, Tawain, Province of China
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Metal-ferroelectric-insulator-semiconductor (MFIS) thin-film structures using PbZr0.53Ti0.47O3(PZT) as the ferroelectric layer and zirconium oxide (ZrO2) as the insulator layer were fabricated in this work. The leakage current and the C-V memory window were measured for MFIS capacitors with the PZT layer annealed at temperatures of 400°C, 500°C, 600°C, 700°C. The dominant conduction mechanism of Al/PZT(290 nm)/ZrO2(15 nm)/Si structure is Poole-Frenkel emission in the temperature range of 300-425 K. Under a sweep voltage of 6 V, the largest memory window of 1.31 V was obtained for 500°C-annealed samples. The memory window as a function of insulator thickness was also discussed. More serious charge injection is observed when the voltage was swept from negative to positive.